G. A. Shar, G. A. Soomro


A first derivative spectrophotometeric determination of cobalt(II) is carried out with 1-nitroso-2-naphthol as complexing reagent in aqueous phase using non-ionic surfactant Tween 40. The cobalt is determined in the range 1.7-120 ng mL-1 with detection limit (2σ) of 1.7 ng mL-1. The molar absorptivity and Sandell's sensitivity are 1.86  104 mol-1cm-1 and 3.6 ng cm-2 at 444.5 nm. The optimum pH of the complexation is 5. The critical micelle concentration (cmc) of Tween 40 is 5 %. Absorption studies in the first derivative mode is carried out to determine the absorption maximum of the complex for higher sensitivity and to overcome interferences. The present method is compared with that of AAS and no significant difference is noted between the two methods at 95 % confidence level. The method has been applied for the determination of Co(II) in pharmaceutical samples.

Full Text:



A.N, Anthemidis, D.G. Themelis and J. A Stratis, Talanta, 54 (2001) 37.

N. Pourreza and S. Rastegarzadeh, Anal. Chim. Acta, 437 (2001) 273.

A. Safavi and H. Abdollahi, Microchem., J., 69, (2001) 69.

S. Gang, C. Xingyuo, Z. Yunkun, L. Mancang and H. Zhide, Anal. Chim. Acta, 420, (2000) 123.

M. P. San Andres, M. L. Marina, and S. Vera, Talanta, 41, (1994) 179.

H. C. Gin, L. Hong and P. J. Mai, Talanta 41, (1994) 1357.

X. Jin, M. Zhu and E.D. Conte, Anal. Chem. 71, (1999) 514.

G. A. Shar, G. A. Soomro and M. I. Bhanger, J. Chem. Soc. Pak., 26, No.2, (2004) 143.

A. K. Malik, K. N. Kaul, B.S. Lark, W. Faubel and A.L.J. Rao, Turk. J. Chem., 25 (2001) 99.

G. A. Shar and M. I. Bhanger, The Nucleus, 39, No. 3-4 (2002) 1.

G. A. Shar and M. I. Bhanger, J. Chem. Soc. Pak 25, No.1, (2003) 28.

J. Yun and H. Choi, Talanta, 52 (2000) 893.

R. L. Sharma and H. B. Singh Talanta 36, No. 4, (1989) 457.

D. D Perrin and B. Dempsey, Buffers for pH and Metal Ion Control, Chapman and Hall, London (1974).

P. Becher, in M. J. Schiek (Ed.) Surfactant Science Series, Vol. 1, Marcel Dekker, New York (1966) p. 481.

H. Khan , M. Jamaluddin and A.M.I. Bhanger Spectroscopy, 20, Nos. 5-6 (2006) 285.


  • There are currently no refbacks.